Thursday, November 28, 2019

THE NEWS Essay Example For Students

THE NEWS Essay Before this assignment I had never studied news coverage before, like I did now. Studying the news that is put out by different news medias is just incredible, because in each type of news service, they are different. The Headlines are usually close to one another but they are not always the exact same. Take the headline for Monday October 19, 1999, CNN Headline News uses New North Carolina flooding feared, while the MSNBC News Headlines are Clinton, GOP in budget showdown, and lastly Lycos News used Computers that Read Your Shifting Moods. Although none of these headline stories are the same, we see what different media outlets believe their headline stories are! I choose three different media outlets they were CNN Headline News, MSNBC Headline News, and one of the search engines Lycos News. The reason why I picked these three different medias is because I thought that they were going to be the most diverse, and the most similar. Because I picked two big media outlets, MSNBC, and CN N Headline News, I thought that these two would probably be closer too each other than Lycos News. The reason why is because each of those two outlets have people everywhere, in the White House, in Bosnia, where ever there is a story they will send people to go. While Lycos is not as dominant as the other two are, I wanted to see how big Lycos really is compared in news coverage. We will write a custom essay on THE NEWS specifically for you for only $16.38 $13.9/page Order now As I said earlier the first report on CNN Headline News was Flooding in North Carolina, the way that CNN had reported this was by two news anchors and a reporter in North Carolina. Because of the time usage of that particular story I as well as other could not believe how big of a story it was. I thought that it was going to be the top story everywhere. I was wrong because MSNBC did not agree with me, because their first story dealt with President Clinton vetoing a 12.6 billion-dollar foreign aid bill. The way MSNBC covered this was by having a reporter in the White House with a Republican as his speaker, and this interview got to be real boring, and not to long. Lycos on the other hand decided that their best story was Computers that read your shifting moods. Lycos decided to send a female reporter Megan Watzke to Cambridge, Massachusetts and report for them. Luckily this news was not on TV because if it were I would have turned it off. MSNBC decided that the flood in North Carolina was there second top story. Although they gave the flood in North Carolina a good amount of network time, it did not seem as good as CNNs report, because they did not have a reporter in North Carolina to really give us an understanding of the area. CNNs next top story was Wary Wall Street eyes earnings reports, this story is a story for the Wall Street businessmen, using the Dow components and earning reports to show that maybe today on wall street might be another rocky ride in the market. CNN also used different people to talk about different markets, like the international and the US market. This type of story is for that six in the morning person who always wakes up and is about to get on the train and go to the Mercantile Exchange. Lycos uses a different headline to talk about the same issue as CNN; they use Crash of 87 Haunts Traders. This story is the mostly the same story as the one on CNN except Lycos goes further back into 1987 and tells more about what happened there. .u831ba1acb0c7244b4b06c16bf30ae564 , .u831ba1acb0c7244b4b06c16bf30ae564 .postImageUrl , .u831ba1acb0c7244b4b06c16bf30ae564 .centered-text-area { min-height: 80px; position: relative; } .u831ba1acb0c7244b4b06c16bf30ae564 , .u831ba1acb0c7244b4b06c16bf30ae564:hover , .u831ba1acb0c7244b4b06c16bf30ae564:visited , .u831ba1acb0c7244b4b06c16bf30ae564:active { border:0!important; } .u831ba1acb0c7244b4b06c16bf30ae564 .clearfix:after { content: ""; display: table; clear: both; } .u831ba1acb0c7244b4b06c16bf30ae564 { display: block; transition: background-color 250ms; webkit-transition: background-color 250ms; width: 100%; opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #95A5A6; } .u831ba1acb0c7244b4b06c16bf30ae564:active , .u831ba1acb0c7244b4b06c16bf30ae564:hover { opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #2C3E50; } .u831ba1acb0c7244b4b06c16bf30ae564 .centered-text-area { width: 100%; position: relative ; } .u831ba1acb0c7244b4b06c16bf30ae564 .ctaText { border-bottom: 0 solid #fff; color: #2980B9; font-size: 16px; font-weight: bold; margin: 0; padding: 0; text-decoration: underline; } .u831ba1acb0c7244b4b06c16bf30ae564 .postTitle { color: #FFFFFF; font-size: 16px; font-weight: 600; margin: 0; padding: 0; width: 100%; } .u831ba1acb0c7244b4b06c16bf30ae564 .ctaButton { background-color: #7F8C8D!important; color: #2980B9; border: none; border-radius: 3px; box-shadow: none; font-size: 14px; font-weight: bold; line-height: 26px; moz-border-radius: 3px; text-align: center; text-decoration: none; text-shadow: none; width: 80px; min-height: 80px; background: url(https://artscolumbia.org/wp-content/plugins/intelly-related-posts/assets/images/simple-arrow.png)no-repeat; position: absolute; right: 0; top: 0; } .u831ba1acb0c7244b4b06c16bf30ae564:hover .ctaButton { background-color: #34495E!important; } .u831ba1acb0c7244b4b06c16bf30ae564 .centered-text { display: table; height: 80px; padding-left : 18px; top: 0; } .u831ba1acb0c7244b4b06c16bf30ae564 .u831ba1acb0c7244b4b06c16bf30ae564-content { display: table-cell; margin: 0; padding: 0; padding-right: 108px; position: relative; vertical-align: middle; width: 100%; } .u831ba1acb0c7244b4b06c16bf30ae564:after { content: ""; display: block; clear: both; } READ: Dinosaurs (1032 words) EssayThe third top story for MSNBC is Pakistan leader reaches out to India. Pakistans military ruler, Gen. Pervez Musharraf said Sunday that he had ordered a unilateral pull back of troops along the nations disputed borders. Now the only reason why I listened is because in politics class we have discussed India and many things about it, but other than that I really do not care for it.CNN Headline news also reported the same thing for their third story; Pakistan begins withdrawal from Indian border. I believe that I saw the same type of coverage on both CNN, and also on MSNBC. Both channels used similar pictures and also very simple word choice to des cribe the situation at hand in Pakistan. Lycos on the other hand decided that US Crime Rate Keeps Sliding, was their third top story. I really like this story because it had said that the murder rate had dropped to the lowest point in thirty-one years. The coverage that they had used on this story was not much; it was about a page at the longest. Though the information that they covered was about the previous highs and lows of the crime rate, and what this means for the future. Lycos decided to use this headline for their fourth news story; Hurricane Irene Swamps North Carolina. The information in this story was just about the same information that I had heard in the other reports from CNN, and MSNBC. The only difference is the way that his story had been chosen. The other media outlets had believed that this was a far bigger story than say Computers that read your shifting moods. CNN Headline News decided to go back to North Carolina and talk to one of the reporters that was their, and try to get a better understanding of what was going on at that current time. I actually started loosing interest in the news at that point because they had just discussed it as their headline story, and now they are going back to it. MSNBC choose Americans confident in military, for their fourth story. This story dealt with the concept of whether or not American troops should be used as peacekeepers in far distant countries. At one point in the story they went to a reporter who was at some Army base, and interviewed a wife of a soldier in the Army. It was nice to see the reaction from her and how she thought her husband felt about the issue. I really like how NBC went out there to hear the reaction from someone who might know better about the issue than us. MSNBC used this headline as its fifth headline U.S. seeks to renegotiate ABM treaty. MSNBC had a reporter in Russia to discuss this treaty. President Clinton and his administration are offering to help complete a large missile tracking radar, if it agrees to alterations to the ABM Treaty to allow an U.S. missile-defense system. What amazed me was that they had a reporter at the White House at first, and then they moved on to another reporter in Russia. Lycos used the headline US Upbeat on Pakistan. This article was on the same grounds as the reports on TV were, it discussed what was going on their, and also reported that troops that were sent to the border during a confrontation over the Kargil moun tains this summer in Kashmir were being withdrawn. No other newscast had reported that, and I felt it quite interesting that Lycos out of them all would be the one to report it. CNN turned their headlines to Clinton, not Bill but Hillary. Hillary Clinton: Probably no announcement till 2000 this was the headline for CNNs fifth story, again they used a reporter from the White House to discuss what Hillarys chances are of running for senate. As the reporter said, he believes that Hillary will run but she said that she would make no comment about it till the year 2000. .u13a832ecbbd9a09583c14764176c003e , .u13a832ecbbd9a09583c14764176c003e .postImageUrl , .u13a832ecbbd9a09583c14764176c003e .centered-text-area { min-height: 80px; position: relative; } .u13a832ecbbd9a09583c14764176c003e , .u13a832ecbbd9a09583c14764176c003e:hover , .u13a832ecbbd9a09583c14764176c003e:visited , .u13a832ecbbd9a09583c14764176c003e:active { border:0!important; } .u13a832ecbbd9a09583c14764176c003e .clearfix:after { content: ""; display: table; clear: both; } .u13a832ecbbd9a09583c14764176c003e { display: block; transition: background-color 250ms; webkit-transition: background-color 250ms; width: 100%; opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #95A5A6; } .u13a832ecbbd9a09583c14764176c003e:active , .u13a832ecbbd9a09583c14764176c003e:hover { opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #2C3E50; } .u13a832ecbbd9a09583c14764176c003e .centered-text-area { width: 100%; position: relative ; } .u13a832ecbbd9a09583c14764176c003e .ctaText { border-bottom: 0 solid #fff; color: #2980B9; font-size: 16px; font-weight: bold; margin: 0; padding: 0; text-decoration: underline; } .u13a832ecbbd9a09583c14764176c003e .postTitle { color: #FFFFFF; font-size: 16px; font-weight: 600; margin: 0; padding: 0; width: 100%; } .u13a832ecbbd9a09583c14764176c003e .ctaButton { background-color: #7F8C8D!important; color: #2980B9; border: none; border-radius: 3px; box-shadow: none; font-size: 14px; font-weight: bold; line-height: 26px; moz-border-radius: 3px; text-align: center; text-decoration: none; text-shadow: none; width: 80px; min-height: 80px; background: url(https://artscolumbia.org/wp-content/plugins/intelly-related-posts/assets/images/simple-arrow.png)no-repeat; position: absolute; right: 0; top: 0; } .u13a832ecbbd9a09583c14764176c003e:hover .ctaButton { background-color: #34495E!important; } .u13a832ecbbd9a09583c14764176c003e .centered-text { display: table; height: 80px; padding-left : 18px; top: 0; } .u13a832ecbbd9a09583c14764176c003e .u13a832ecbbd9a09583c14764176c003e-content { display: table-cell; margin: 0; padding: 0; padding-right: 108px; position: relative; vertical-align: middle; width: 100%; } .u13a832ecbbd9a09583c14764176c003e:after { content: ""; display: block; clear: both; } READ: Slavery3 EssayI have taken three types of news media outlets and broke them down into different parts. I have discussed what was chosen; the number it was put on air, and many other things about news media. Although this essay was one of the hardest that I have written, I have learned a lot about different types of news, why some news is put on before, and I also got to watch TV. Since the year 2000 is coming up, and plus we have election in the year 2000, the news is going to play a crucial part in the election for a President. Bibliography:

Monday, November 25, 2019

Small Group Reflection Essays

Small Group Reflection Essays Small Group Reflection Essay Small Group Reflection Essay Small group and team communication is basically the most imperative skill that any individual will ever have to learn. Communication consists of making contact with other individuals in verbal or nonverbal connection. Whether it is a group or team each individual has different background and customs, therefore he or she should be confident enough to deal with social diversity because there is no particular way in dealing with such diverse groups. The importance of team communication is vital for achievement because people learn from one another and share similar objectives. While classroom lectures provide students with volumes of information, many experiences can be understood only by living them. It is with the? workings of a small, task-focused group. What observations can I make after? working with my group? And what have I learned as a result? When meeting together and brainstorming ideas for our can drive there were many leadership roles and? the strengths of our individual group that became increasingly apparent. Although? early in our project Jeff was the key initiator and Casey largely an information? seeker, all of us group members eventually took on these functions in addition to? erving as recorders, gathering information, and working on coming up with ideas on how we would start and initiate this can drive. Every member coordinated the group’s work at some point, several made sure that? everyone could speak and be heard, and Casey was especially good at? catching important details the rest of us were oblivious to. Tyler and I frequen tly clarified or elaborated on information, whereas Andrea, Casey, and Jeffrey were good at contributing ideas during brainstorming sessions. Casey, Jeffrey and I brought tension-relieving humor to the group.? Just as each member brought individual strengths to the group, gender? differences also made us effective. For example, Andrea and Casey looked at the big picture and made intuitive leaps in? ways that the Jeffrey, Tyler, and I generally did not. Brilhart and Galanes have suggested that men working in groups? dominated by women may display â€Å"subtle forms of resistance to a dominant? presence of women† (p. 98). Our differing qualities complemented each other and enabled? us to work together effectively. The formation of our group developed in four stages. The first was the Forming stage in which we were uncertain about our roles and who to trust. This beginning stage is relatively where we as group members introduced ourselves. At this stage we were unsure how we would be able to use each other’s experience and abilities to come together as a cohesive group. The following stage was Storming, which is a time we learned about expectations discussed then confirmed by each one of us. The third stage of our development was Norming, a stage of working together to reach our goals. Lastly, the Performing stage is focused on solving any problems that arise. This stage is critical for getting the project done on time and completing the goal. Our group had a sense of unity that went through developmental stages. Each Learning Team member played a different role and it was important for us to perform his or her duties in order to get maximum cooperation between each member. Through these maintenance roles better relationships developed and improved morale of the group cooperation. In order for our group to develop into a well performing group organization we needed to have and maintain certain characteristics. We are a group of students with a vision working towards a common goal. The building of our team was complicated. We negotiated roles and tasks according to our strengths and interests. We worked well together, but far from perfect. Ideas were exchanged and meaningful productivity resulted. Good communication resulted from trust and respect. All of us members shared an equal participation, which made it easier for each individual to contribute to the success. Brilhart, J. K. , Galanes, G. J. (1998). Effective group discussion (9th ed. ). Boston:? McGraw-Hill.

Thursday, November 21, 2019

Explain how understanding culture can clarify and affect the reading Essay

Explain how understanding culture can clarify and affect the reading of a text - Essay Example In doing this, culture affects and often clarifies the reading of such texts as is portrayed in the analysis of Oedipus and The Iliad below. The two are among the greatest literatures of the ancient Greek. The literatures capture various cultural features of the ancient Greek societies and therefore require an understanding of the early Greek culture to comprehend. The Iliad for example is set during the Trojan War (Homer 23). War was a central cultural feature that enabled societies to interact as they resolved their conflicts. The ambience of wars at the time was different from the contemporary wars. As a cultural feature, understanding the nature of the ancient Greek wars enables an audience understand the book since the wars would clarify the types of weapons the people used and the severity of the wars. The epic poem voices tales of clashes and the events preceding the war. The quarrels between King Agamemnon and Achilles help portray the cultural feature of the ancient Greek societies. Another cultural trait in the tragedy Oedipus the King is prophecy. Set in the ancient Greek society the mythology portrays the effects of prophecies in an individual’s life. The prophecies were vital aspects of life since they affected the lives of everyone including the King (Sophocles 12). The portrayal of prophecy presents an ultimate conflict in the story between the will and destiny. As such, understanding the ancient Greek culture becomes essential in understanding the story. The prophecy in the story clarifies the actions of Oedipus who accidentally kills his parents thereby fulfilling the prophecy. The act leads to other subsequent occurrences the play. Culture helps clarify relationship between the events thus implying that culture helps develop the conflict that sustains the story. The role of an Individual in the course of destiny is a theme in both ancient books. Additionally, the authors portray harsh societies in both books a feature that

Wednesday, November 20, 2019

The Foundation of Orthodoxy and the Canon Research Paper - 1

The Foundation of Orthodoxy and the Canon - Research Paper Example Bauer, one of the most remarkable scholars of early Christianity, refutes the view that Jewish tendency in the formation of Christian canon was limited to the activities of Ebionites. He turns attention to the Syrian Jewish communities and the writings like Kerigmata Petrou and Didascalia that interpret Jesus as a â€Å"true prophet† and rely on the Peter’s Gospel while dismissing Paul’s views2. Jewish writings in general tended to favor Matthew and disregard Paul, as Paul was one of the most active proponents on the independence of Christian doctrine from the Old Testament code of conduct (the diet, circumcision, and a holiday once a week prescribed by it)3. Matthew’s Gospel openly demands the acceptance of Jewish Law; that is why it was largely supported by different early Jewish Christian movements4. The most influential of the latter were Ebionites (one of the possible etymological explanations of this name is its connection with the ideal of humble, p oor living), the supporters of the â€Å"adoptionist† doctrine: to them, Jesus was a human being â€Å"adopted† by God, an ideal sacrifice after which other sacrificial rituals were not needed any more5. From this followed that Ebionites excluded the first chapters of Gospels that told the story of Christ’s birth to Virgin and that they did not consume meat6. Their doctrine in oral form was based on Matthew’s Gospel in Aramaic; later, the Gospel of Ebionites in Greek appeared for the generation unfamiliar with Aramaic7. The first attempt of the canonization of writing about Christ was actually made by a heretic who opposed the Jewish doctrine, the one named Marcion. His rationale was to challenge the view of God in the Old Testament and to comment the New Testament as the rejection of the older doctrine, â€Å"a Gospel of Love to the exclusion of Law†8. Like many Orthodox theologians of the time, he accepted the Gospel according to Luke and the epi stles by Paul with slight changes and modifications by Marcion himself; some of his changes remained in the later Pauline and Lukan texts9. The first time Marcion declared his ideas was 144 CE, on the Christian Congregation in Rome10. Marcion rejected the entire Old Testament and the epistles of all apostles but Paul; he saw Jesus Christ as the son of Supreme God of love and grace, not punishment and justice, and claimed that this son only looked like a human being, so that the first chapters of Luke were viewed as misleading about His coming to the human world (not embodiment)11. He also deleted some parts of the text of the Gospel and epistles (like Gal.iii. i6 – iv.6 and 2 Thess. i. 6-8) on the ground that they supported the older Jewish tradition of Law12. Marcion produced his own polemic text and, as some of the Christian historians have proved, the introductory paragraphs to some of the epistles in Vulgata13. Marcion’s vision was very attractive because of the em phasis on mercy; it was very popular among Gentiles who were not native Jews14. Ehrman speculates about the possible prospects of Christianity influenced by either Marcionism

Monday, November 18, 2019

From the door Essay Example | Topics and Well Written Essays - 500 words

From the door - Essay Example Analysis: The person who tells the story in A Rose for Emily remains unidentified throughout the story. Some readers may be of the view that the narrator is the boy that stores memories of Mr. Grierson as he stood in the doorway. Some readers may also identify the narrator as the former servant of Emily, named Tobe, given he had spent quite some time with Emily watching her intimately. However, Tobe gets vanished in the end while the narrator keeps narrating. This provides assurance for the idea that the narrator can not be Tobe. In fact, voice of the narrator is the gossip of the town that tends to make its way through the door of Emily’s house. A deep analysis of the story suggests that the unnamed narrator is indeed, the collective and unified voice of the whole town because it is no one but the townspeople, who stay until the end of the story and explore Emily’s secret. Many events that have a fundamental role in the building up of plot happen to occur inside Emily Grierson’s house. The outsiders often have no access to the events that happen behind the closed doors, though the curiosity among the town people to learn about the world inside Emily’s house is immense.

Friday, November 15, 2019

Preparation of Recrystallization of Aspirin

Preparation of Recrystallization of Aspirin 1. Synopsis This experiment serves 2 objectives the production of Aspirin from esterification of salicylic acid with excess acetic anhydride and obtaining it in a purer state by recrystallisation, hence determines the melting point of the acetylsalicylic acid (ASA) that was synthesised and purified. To achieve this, salicylic acid is reacted with excess acetic anhydride in the presence of the sulphuric acid as the catalyst, which produces precipitate ASA and aqueous acetic acid. I applied suction filtration to collect the ASA as the residue having acetic acid as the filtrate. Pure aspirin is a white crystalline solid. The aspirin initially produced by synthesis may be light tan, indicating the presence of impurities. The ASA synthesis earlier is purified by recrystallization. In recrystallization, the impure solid is dissolved in a hot solvent (aqueous ethanol) and the resulting solution is allowed to cool slowly. As the solution cools, crystals of the product will form and soluble impurities will remain in solution. From this experiment, the percentage yield of ASA is around 49%, using capillary test the melting point of ASA falls in the rage of 137.9-140.5 0 C. The appearance of ASA is an odourless, white, needle-shaped and shiny solid. In conclusion, experiment is a success. Despite product had a low percent yield and was found to be impure due to its low melting point. 2. Introduction Aspirin is the trade name for the molecule acetylsalicylic acid. The earliest known use of this molecule has been traced back to the fifth century B.C. The Greek physician Hippocrates described an extract of willow tree bark, a bitter powder that could be used to reduce fevers. In 1829, Salicin was isolated from willow bark and used as a pain reliever. Unfortunately Salicin was not very popular since it was found to be very acidic and a stomach irritant. In 1897 Felix Hoffman, a German chemist, was working for the Bayer chemical company. Hoffman wanted to formulate for a less acidic pain reliever as his father could consume for his arthritis. His studies led to the synthesis of acetylsalicylic acid (ASA) or aspirin. Bayer patented the name and commenced to market the product in 1899. It was a huge success and sales grew rapidly. In fact, the company set up by Friedrich Bayer Company is generally considered to have been the first pharmaceutical company, and the production of aspirin has indisputably laid the base of the modern pharmaceutical industry. Only until the 1970s that scientists starts to comprehend the concept on how aspirin function as a pain reliever. Today 80 billion aspirin tablets are taken every year over the al the countries to reduce fevers, relieve pain, and even help prevent heart attacks. Bayer In commercial aspirin products, a small amount of ASA (300 to 400 mg) is bound together with a starch binder and sometimes caffeine and buffers to make an aspirin tablet. The basic conditions in the small intestine break down the ASA to yield salicylic acid, which is absorbed into the bloodstream. The addition of a buffer reduces the irritation caused by the carboxylic acid group of the aspirin molecule. 3. Theory Esters are organic compounds with the general formula RCOOR, where R and R can be an alkyl group or an aromatic group. Alkyl group is an alkane that is short of one hydrogen since it needs one bond to be branched from the parent chain. Aromatic compounds are a class of molecules containing benzene, a six-membered carbon rings with delocalized pi electrons. This type of group is found in salicyclic acid and ASA. Esters are readily synthesized by the reaction between a carboxylic acid, RCOOH, and an alcohol, ROH, as shown in the following reaction. The reaction above is also known as esterification. It is a condensation reaction, whereby two molecules combine to form one single molecule, while removing a small molecule (e.g. H2O) in the process. The reaction to I have used synthesis ASA is very similar to the one above. Salicylic acid a phenol consisting of a phenyl bonded to the hydroxyl (-OH) which is very much alike to alcohol and acetic Anhydride is a dehydrated carboxylic acid (acetic acid). In the below reaction we use concentrated sulphuric acid as the catalyst. After the warm bath to complete the reaction, we added cold water to quench the reaction (hydrolysis of acetic anhydride) to prevent further reaction to take place. The cold water must be added quickly as to allow fast crystal formations due to the drastic drop in temperature. Stir and rub the walls can create uneven surfaces hence inducing crystallization. ). As such, in this experiment, 2.4 grams of salicylic acid should yield 3.13 grams of Aspirin, it is stated that acetic anhydride is in excess. This is proven by the following calculation: Mol of salicylic acid in this experiment: 2.4(2d.p)/138 = 0.0174 (3 s.f.) Mol of salicylic acid : Mol of Aspirin 1 : 1 Therefore, Mol of Aspirin: 0.0174/1 x 1 = 0.0174 (3 s.f.) Expected mass of Aspirin: 0.017391 x 180 = 3.130 (3 dec.) The solid ASA formed contains impurities and should be recrystallised to achieve a purer state. Recrystallization is possible because most solids are more soluble in hot solvents than in cold solvents. The solubility of ASA increases as temperature increases. This means that if aspirin is dissolved in ethanol to produce a saturated solution and that solution is cooled, the aspirin will crystallize during the cooling. Ethanol has been chosen as the solvent because the polar nature of the hydroxyl group causes ethanol to dissolve many ionic compounds, moreover the ethanol molecule also has a non-polar end, and it will also dissolve non-polar substances. While cooling, crystallization takes place. In crystallization, there is a slow, selective formation of the crystal framework resulting in a pure compound. Instead in precipitation, due to the rapid formation it will trap impurities in the solids crystal framework. For this reason, we should include crystallization to get a purer solid substance. The alternate way of synthesising the aspirin can be produced by replacing the acetylating agent from acetic anhydride to an even more acidic acid known as acetyl chloride CH3COCl. This can increase the percentage yield of ASA, since acetyl chloride is more acidic. The reaction of acetyl chloride with salicylic acid is showed below. However, the by-product is hydrochloric acid (HCl) instead of acetic acid. However, Acetic anhydride is preferred because it is less hazardous to use and less expensive than acetyl chloride. In industry, the acetic acid produced in this reaction can be recovered and converted back into acetic anhydride by the process known as dehydration: We may also create or Salicylic acid from Kolbes reaction whereby we start with a phenol: 4. Procedure Approximately 2.4 grams of salicylic acid is weighed and placed in a dry, 100ml conical flask. 6ml of acetic anhydride is added into the same conical flask, along with 3-4 drops of concentrated H2SO4 as catalyst. The conical flask is then heated at 80-100 degree C in a water bath for 10 to 15 minutes to hasten the reaction. 1ml of distilled H2O is added into the conical flask immediately after it is removed from water bath. 40ml of cold distilled H2O is then added to the conical flask. A stirring rod is used to gently rub the side of the conical flask. This is to scratch off crystals which have formed. Suction filtration is then carried out to remove the crystals from the solution. The crystals are removed from the filter paper. To ensure accuracy, cold distilled H2O is used to wash away remaining crystals from the filter paper. The crystals are then dissolved in 5ml of ethanol. 30ml of hot, distilled H2O is added into the solution, and slowly cooled. Crystallisation of Aspirin will take place as the solution is cooled to room temperature. Suction filtration is done to remove the Aspirin from the solution. The residue is then placed on a watch glass along with the filter paper. Aspirin is then dried by placing it in the oven for 20 minutes, along with the watch glass and filter paper. It will then be transferred to the desiccators for 15 minutes to further dry it. The crystals remained on the filter paper would be pure, dry, Aspirin. The following measurements are taken: Actual weight of salicylic acid is weighed at (1). Weight of filter paper and watch glass is taken. Weight of Aspirin, along with watch glass and filter paper, is taken after (15). After obtaining Aspirin, the melting point of Aspirin is then determined using the capillary method. 5. Results and Calculation Mass Mass of salicylic acid (a) = 2.39 g Mass of filter paper watch glass (b) = 33.11 g Mass of dried, recrystallised aspirin, filter paper watch glass (c) = 34.64 g Mass of dried, recrystallised aspirin (d) = (c) (b) = 34.64-33.11 = 1.53 g Percent yield Number of moles of salicylic acid used (e) = 0.0173 mol (Molecular weight of salicylic acid = 138) Expected number of moles of aspirin (f) = 0.0173 mol Expected mass of aspirin (g) = 3.12 g (Molecular weight = 180) Melting point Temperature range 137.9-140.5Â °C Appearance Needle shaped, white, and shiny. 6. Discussion My percentage yield ASA is relatively low since it is only 49%. This may occur due to several factors: While transferring the salicylic acid, some of the solid may stay at the side of the conical flask and even your spactula, and resulting in lesser salicylic acid participating in the process of esterification compared to what have been weighed earlier. Thus, this will result in lower yield of the crystal ASA. It will be advisable to wash the walls with distilled water to ensure more salicylic acid will participate in the reaction. When dissolving the initial amount of salicylic acid in the solution of acetic anhydride and concentrated sulphuric acid, it did not completely dissolve into the solution, even when it was heated. This could have a slight impact on the results of the overall yield of aspirin because it was possible that not all of the salicylic acid was synthesized. To determine if this affected the synthesis of aspirin at all, the experiment should have been ran a second time to see if the same thing occurred. The iron (III) chloride test also could have been ran to determine if any of the aspirin degraded to salicylic acid or never converted from salicylic acid. During the suction filtration we should rinse the solid ASA formed in the conical flask and the glass rod during the synthesis before pouring into the BÃ ¼chner funnel repeatedly. After the final suction filtration, another error causes the percentage yield to drop. This is due to the crystals not being fully collected on the filter paper, but rather, remains on the side of the Buchner funnel. This loss can be minimized by the crystals from the side of the BÃ ¼chner funnel to the filter paper moving using a metal spatula before collecting the filter paper and placing it on the watch glass. During recrystallization, one common error of adding too much solvent (ethanol) will result in less percentage yield while cooling. We should refrain from moving or shifting the solution while it is cooling as it will interrupt the crystal formation since the particles are generally held by weak dispersion forces, dipole-dipole forces, and hydrogen bond. We should also allow slow crystal formation as fast crystal formation will cause the trap of impurities and giving higher percentage yield. With the presence of impurities the melting point will decrease and vary in a larger range. 7. Conclusion In conclusion, the experiment is a success since I have managed to synthesis and recrystallise the ASA although we have relatively low percentage yield of 49% that may arise due to several factors as stated in the discussion. I was able to analysis the melting point of the recrystallised aspirin and it is generally low in temperature which implies the presence of impurities.

Wednesday, November 13, 2019

Betrayal :: Personal Narrative Writing

Betrayal 1.Desire It is easy to fall in love with bodies. I Breathe skin, lose time to anticipation and pleasure, hair, lips, thighs; tangled in another person, I am lost in a jungle. Transcendence. Society teaches us to break a body down: we love legs, butts, breasts; we take images and splice them into the form of our perfect desire. Like Pygmalion we are desperate to breathe life into our conception of beauty, our imagination of a perfect creature. Reality is easily redrawn around a body whose presence in a place reorganizes the map of the world. Nothing exists but the texture of skin, its taste thick in the mind's imagination. Against our animal world, ideas and numbers seem strange, misplaced, insignificant to desire and love, to connecting with another's warmth. Trying to fulfill a fantasy, it is the dreamer who is recreated. It is time that is filled in. 2. Characters To a moment we are only characters. In this moment: David, the long-term boyfriend (now). Moa, at first betrayer, then clown, then you (then). There is the self who perceives, creates, and ultimately longs for the deep and endless fall of vertigo (lost between the now and then). And there is Love, so mysterious and evasive that I sometimes believe it is a character, alive, weaving tendrils around us (love plays with time). But the descriptions might switch names. I could be the clown, and it could be you who plunges yourself into vertigo. And maybe only one character could play all the parts. There are several combinations to fit several moods (this is my version that fits my now). 3. Eternity The moment has a way of leaking into other moments. Other moments with other lovers leak into the memory. The lovers, like muddying watercolors, swirl into each other. I wonder if I only have relationships with myself. I ask myself the same question over and over till it feels like I am banging my head against a wall, "What do I want?" I look into my heart but it is hard to see through the haze of time and desire. Sartre writes that we are indoctrinated with the values of our societies. We can never be or know ourselves till we escape these. Sartre draws one single path to freedom, this is radical choice, choosing something totally unconnected to anything, in practice this could only be a random choice.